تست

A
. See alpha. aberration, spherical. The aberration by
which light passing through the edge of a lens with
spherical surfaces comes to focus in a different im-
A. Abbreviation for absolute temperature.
age plane from that passing through the lens center.
A
˚
. Abbreviation for A
˚
ngstrom.
abherent. Any substance that prevents adhesion
of a material to itself or to another material. It may be
a. Abbreviation for atto-, a prefix meaning 10
18
in the form of a dry powder (a silicate such as talc,
unit.
mica, or diatomaceous earth); a suspension (benton-
ite-water); a solution (soap-water); or a soft solid
AAAS. See American Association for the Ad-
(stearic acid, tallow waxes). Abherents are used as
vancement of Science.
dusting agents and mold washes in the adhesives,
rubber, and plastics industries. Fats and oils are used
AATCC. See American Associates of Textile
as abherents in the baking industry. Fluorocarbon
Chemists and Colorists.
resin coatings on metals are widely used on cooking
utensils.
abaca. (Manila hemp). The strongest vegetable
See antiblock agent; dusting agent.
fiber, obtained from the leaves of a tree of the banana
family. The fibers are 4–8 feet long, light in weight,
Abies Siberica oil. See fir needle oil.
soft, lustrous, and nearly white; they do not swell or
lose strength when wet. Denier ranges from 300 to
abietic acid. (abietinic acid; sylvic acid).
500. Combustible, but self-extinguishing.
CAS: 514-10-3. C
19
H
29
COOH (having a phenan-
Source: Philippines, Central America, Sumatra.
threne ring system). A major active ingredient of
Use: Heavy cordage and twine, especially for marine
rosin, where it occurs with other resin acids. The
use; manila paper.
term is often applied to these mixtures, separation of
See hemp.
which is not achieved in technical grade material.
Properties: Yellowish, resinous powder. Mp
abate. (O,O-dimethyl phosphorothioate-O,O-
172–175C, optical rotation 106. Soluble in alco-
diester with 4,4
-thiodiphenol; temephos).
hol, ether, chloroform, and benzene; insoluble in
CAS: 3383-96-8. [(CH
3
O)
2
PSOC
6
H
4
]S.
water. Combustible.
Properties: Colorless crystals. Mp 30C.
Derivation: Rosin, pine resin, tall oil.
Hazard: Toxic by ingestion and inhalation. Cholin-
Method of purification: Crystallization.
esterase inhibitor. TLV: 10 mg/m
3
.
Grade: Technical.
Use: Pesticide.
Use: Abietates (resinates) of heavy metals as varnish
driers, esters in lacquers and varnishes, fermentation
Abbe´ condenser. Substage two-lens condenser
industries, soaps.
giving numerical aperture of 1:20–1:25. Three-lens
versions give numerical aperture of 1:40.
“Abitol” [Aqualon]. TM for a colorless, tacky,
very viscous liquid; mixture of tetra-, di-, and dehy-
Abbe´ number. (1) The reciprocal of dispersive
droabietyl alcohols made from rosin.
power. (2) The measure of optical dispersion of a
Use: Plasticizers, tackifiers, adhesive modifiers.
glass; the measure of two planes not displacing the
axis.
ablation experiment. An experiment designed
to produce an animal deficient in one or a few cell
Abegg’s rule. The solubility of salts of alkali
types in order to study cell lineage or cell function.
metals decreases in strong acids and increases in
The idea is to make a transgenic mouse with a toxin
weak acids as atomic weight increases. This is an
gene (often a diphtheria toxin) under control of a
empirical rule; sodium chloride is an exception.
specialized promoter which activates only in the
target cell type. When embryo development pro-
Abel-Pensky flash-point apparatus. In-
gresses to the point where it starts to form the target
strument used for the determination of the flash
tissue, the toxin gene is activated, and the target
point of petroleum.
tissue dies. Other tissues are unaffected.
aberration. Deviation from the ideal in an opti- ablative material. Any material that possesses
cal system, the image points being imperfect or a capability for rapidly dissipating heat from a sub-
improperly located. strate. Specialized ceramic tiles developed since
1
2ABRAM’S LAW
1980 for protection of the space shuttle have proved ing material to the aluminum, with application of
successful. The materials used are of two major heat and pressure.
types: (1) Fibers made from white silica, fused in an
oven, cut into blocks, and coated with borosilicate
abrasive, coated. See abrasive (2).
glass; these are extremely efficient at temperatures
up to 2300F. (2) An all-carbon composite (called
ABS. Abbreviation for (1) alkyl benzene sulfo-
reinforced carbon-carbon) made by laminating and
nate (detergent); (2) acrylonitrile-butadiene-styrene
curing layers of graphite fiber previously coated
copolymer.
with a resin, which is pyrolized to carbon. The re-
See ABS resin.
sulting tile is then treated with a mixture of alumina,
silicon, and silicon carbide. Such composites are
abscisic acid.
used for maximum-temperature (nose-cone) expo-
CAS: 21293-29-8. C
15
H
20
O
4
. A plant growth regula-
sure up to 3000F. Both types are undamaged by the
tor that promotes detachment of leaves and fruit.
heat and are reusable. The tiles are adhered to the
Properties: Colorless crystals. Mp 160C. Sublimes
body of the spacecraft with a silicone adhesive.
at 120C. Soluble in acetone, ether, chloroform;
Ablative materials used on early spaceship trials
slightly soluble in water. Optically active.
were fluorocarbon polymers and glass-reinforced
Occurrence: In plants, fruits, and vegetables from
plastics, but these were wholly or partially decom-
which it can be extracted. Also made synthetically.
posed during reentry.
Use: In orchard sprays to facilitate fruit harvesting,
defoliant, growth inhibitor.
Abram’s law. The strength of concrete depends
on the water/cement ratio.
absinthium. (wormwood). C
30
H
40
O
7
. An essen-
tial oil with intensely bitter taste due to presence of
abrasion. Gradual erosion of the surface of a
absinthin.
material both by physical forces (simultaneous cut-
Hazard: Toxic by ingestion.
ting, shearing, and tearing) and by chemical degra-
Use: A flavoring in liqueurs, vermouth.
dation, chiefly oxidation. Temperature is a signifi-
cant factor: friction may raise the temperature of the
surface layers to the point where they become sub-
absolute. (1) Free from admixture of other sub-
ject to chemical attack. Abrasion causes deteriora-
stances; pure. Example: absolute alcohol is dehy-
tion of many materials, especially of rubber (tire
drated ethanol, 99% pure. (2) The pure essential oil
treads), where it can be offset by a high percentage
obtained by double solvent extraction of flowers in
of carbon black; other materials subjected to abra-
the manufacture of perfumes.
sion in their service life are textiles (laundering),
See concrete (2). (3) absolute temperature.
leather and plastics (shoe soles, belting), and house
paints and automobile lacquers (airborne dust, grit,
absolute configuration. The configuration of
etc.).
four different substituent groups around an asym-
See abrasive.
metric carbon atom. The absolute configurations of
molecules in biochemistry are compared to the con-
abrasive. A finely divided, hard, refractory mate-
figuration of d- and l-glyceraldehyde.
rial, ranging from 6 to 10 on the Mohs scale, used to
reduce, smooth, clean, or polish the surfaces of oth-
absolute error. The actual difference between
er, less hard substances, such as glass, plastic, stone,
the approximate and the exact value in any calcula-
wood, etc. Natural abrasive materials include dia-
tion.
mond dust, garnet, sand (silica), corundum (alumi-
num oxide, emery), pumice, rouge (iron oxide), and
absolute temperature. The fundamental tem-
feldspar; the more important synthetic types are
perature scale used in theoretical physics and chem-
silicon carbide, boron carbide, cerium oxide, and
istry, and in certain engineering calculations, such as
fused alumina. Abrasive in powder form may be (1)
the change in volume of a gas with temperature.
applied directly to the surface to be treated by me-
Absolute temperatures are expressed either in de-
chanical pressure or compressed-air blast, as in cle-
grees Kelvin or in degrees Rankine, corresponding
aning building stone; (2) affixed to paper or textile
respectively to the centigrade and Fahrenheit scales.
backing after the particles have been coated with an
Temperatures in Kelvins are obtained by adding 273
adhesive; or (3) mixed with a bonding agent such as
to the centigrade temperature (if above 0C) or sub-
sodium silicate or clay, the particles being com-
tracting the centigrade temperature from 273 (if
pressed into a wheel rotated by a power-driven shaft.
below 0C). Degrees Rankine are obtained by sub-
Aluminum grinding wheels are fabricated by bond-
tracting 460 from the Fahrenheit temperature.
ing industrial diamonds with fluorocarbon polymer
(“Teflon”). The process involves reaction of fluo-
rine with the surfaces of the diamonds, chemical
absolute zero. Temperature at which the vol-
bonding of the fluorinated diamonds to the fluoro- ume of a perfect gas theoretically becomes zero and
carbon, and further chemical bonding of the result- all thermal motion ceases: 273.13C or 459.4F.
3 ABUNDANCE
absorbent. (1) Any substance exhibiting the Absorption processes occur throughout the electro-
property of absorption, e.g., absorbent cotton, so magnetic spectrum, ranging from the region (nu-
clear resonance absorption or the Mossbauer effect)
made by removal of the natural waxes present. (2) A
to the radio region (nuclear magnetic resonance). In
material that does not transmit certain wavelengths
practice, they are limited to those processes that are
of incident radiation.
followed by the emission of radiant energy of great-
See absorption (1); absorption (2).
er intensity than that which was absorbed. All ab-
sorption processes involve absorption of a photon by
absorptiometer. An instrument for determining
the substance being analyzed. If it loses the excess
the solubility of a gas in a liquid.
energy by emitting a photon of less energy than that
absorbed, fluorescence or phosphorescence is said
absorption. (1) In chemical terminology, the
to occur, depending on the lifetime of the excited
penetration of one substance into the inner structure
state. The emitted energy is normally studied. If the
of another, as distinguished from adsorption, in
source of radiant energy and the absorbing species
which one substance is attracted to and held on the
are in identical energy states (in resonance) the ex-
surface of another. Physicochemical absorption oc-
cess energy is often given up by the nondirectional
curs between a liquid and a gas or vapor, as in the
emission of a photon whose energy is identical with
operation known as scrubbing, in which the liquid is
that absorbed. Either absorption or emission may be
called an absorption oil; sulfuric acid, glycerol, and
studied, depending upon the chemical and instru-
some other liquids absorb water vapor from the air
mental circumstances. If the emitted energy is stud-
under certain conditions. Physiological absorption
ied, the term resonance fluorescence is often used.
takes place via porous tissues, such as the skin and
However, if the absorbing species releases the ex-
intestinal walls, which permit passage of liquids and
cess energy in small steps by intermolecular colli-
gases into the bloodstream.
sion or some other process, it is commonly under-
See adsorption; hygroscopic. (2) In physical termi-
stood that this phenomenon falls within the realm of
nology, retention by a substance of certain wave-
absorption spectroscopy. The terms absorption
lengths of radiation incident upon it, followed either
spectroscopy, spectrophotometry, and absorptime-
by an increase in temperature of the substance or by
try are often used synonymously. Most absorption
a compensatory change in the energy state of its
spectroscopy is done in the ultraviolet, visible, and
molecules. The UV component of sunlight is ab-
infrared regions of the electromagnetic spectrum.
sorbed as the light passes through glass and some
See emission spectroscopy; infrared spectroscopy.
organic compounds, the radiant energy being trans-
formed into thermal energy. The radiation-absorp-
tive capacity of matter is utilized in analytical chem-
absorption tower. (scrubber; Paulson tower).
istry in various types of absorption spectroscopy. (3)
A device used for gas purification by absorption of
In physical chemistry, the ability of some elements
gas impurities in a liquid.
to pick up or “capture” thermal neutrons produced in
nuclear reactors as a result of fission. This is due to
ABS resin. Any of a group of tough, rigid ther-
the capture cross section of their atoms, which is
moplastics that derive their name from the initial
measured in units called barns; elements of particu-
letters of the monomers which produce them.
larly high neutron absorption capability are cadmi-
um and boron.
abstraction reaction. A reaction that removes
an atom from a structure.
absorption (biology). Transport of the prod-
ucts of digestion from the intestinal tract into the
abundance. The relative amount (% by weight)
blood.
of a substance in the earth’s crust, including the
atmosphere and the oceans. (1) The abundance of
absorption band. The range of wavelengths
the elements in the earth’s crust is:
absorbed by a molecule; for example, absorption in
the infrared band from 2.3 to 3.2 m indicates the
Rank Element % by wt.
presence of OH and NH groups, while in the band
from 3.3 to 3.5 indicates aliphatic structure. Atoms
1 Oxygen 49.2
absorb only a single wavelength, producing lines,
2 Silicon 25.7
such as the sodium D line.
3 Aluminum 7.5
See spectroscopy; resonance (2); ultraviolet absorb-
4 Iron 4.7
er; excited state.
5 Calcium 3.4
6 Sodium 2.6
absorption oil. See absorption (1).
7 Potassium 2.4
8 Magnesium 1.9
absorption spectroscopy. An important tech- 9 Hydrogen 0.9
nique of instrumental analysis involving measure- 10 Titanium 0.6
ment of the absorption of radiant energy by a sub- 11 Chlorine 0.2
stance as a function of the energy incident upon it. 12 Phosphorus 0.1
4“ABZOL”
“Accepta” [Accepta]. TM for a rig wash con-
Rank Element % by wt.
centrated detergent miscible with fresh or sea
waters.
13 Manganese 0.1
Use: Cleaning in the shipping industry.
14 Carbon 0.09
15 Sulfur 0.05
“Accepta 3538” [Accepta]. TM for an emul-
16 Barium 0.05
sifying bilge cleaner and degreaser.
all others 0.51
(2) The percentages of inorganic compounds in the
“Accepta 3547” [Accepta]. TM for a water
earth’s crust, exclusive of water, are:
stain and scale remover.
(1) SiO
2
55 (2) Al
2
O
3
15 (3) CaCO
3
8.8
Use: For steel, wood, glazed surfaces, toilet bowls,
(4) MgO 1.6 (5) Na
2
O 1.6 (6) K
2
O 1.9
baths and terrazo.
(3) The most abundant organic materials are cellu-
lose and its derivatives, and proteins.
acceptability (foods). See organoleptic.
Note: In the universe as a whole, the most abundant
element is hydrogen.
acceptable risk. A concept that has developed
in recent years, especially in connection with toxic
“Abzol” [Albemarle]. TM for a solvent cleaner
substances (insecticides, mercurials, carcinogens),
that can be used in place of